Nuclear magnetic resonance measurements of equilibria involving hydration and hemiacetal formation from some carbonyl compounds
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic
- p. 169-170
- https://doi.org/10.1039/j29670000169
Abstract
Nuclear magnetic resonance measurements have been made of equilibria involving addition of water, sodium hydrogen sulphite, and substituted alcohols to aldehydes and ketones. The accuracy compares favourably with that of spectrophotometric measurements. The variation in degree of reaction is discussed in terms of known electronic and steric effects.Keywords
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