Photofragmentation of (CO2)+n: Simple energy dependence for the number of neutrals ejected, 13<n<26
- 1 June 1985
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 82 (11) , 5288-5289
- https://doi.org/10.1063/1.448605
Abstract
Ionic photofragmentation patterns of (CO2)+n, 2<n2 molecules lost increases smoothly with cluster size, approaching a constant value that depends linearly on the photon energy. A model for involving sequential loss of CO2 monomers is indicated, and the average CO2‐cluster bond energy is found to be constant at 4.9 kcal/mol for n>13.Keywords
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