Time resolved energy transfer from electronically excited 3B3u pyrazine molecules to planar Ag and Au surfaces
- 15 January 1982
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 76 (2) , 1146-1149
- https://doi.org/10.1063/1.443083
Abstract
The lifetime of 3B3u pyrazine near Ag surfaces has been measured down to a separation of ∼35 Å, where it has decreased by a factor of ∼600 from the isolated molecule value. There is no evidence for saturation of the energy transfer rate. The technique and apparatus are described. Numerical solutions to the classical double interface theory of energy transfer show energy transfer rates should be sensitive to adsorbed gas on top of the excited molecule.Keywords
This publication has 10 references indexed in Scilit:
- Long range vibrational energy transfer to dielectric surfacesThe Journal of Chemical Physics, 1981
- Electronic energy transfer to metal surfaces: a test of classical image dipole theory at short distancesChemical Physics Letters, 1980
- Application of classical electromagnetic theory to an understanding of molecular vibrational energy transfer into metal surfacesThe Journal of Chemical Physics, 1980
- Time resolved molecular electronic energy transfer into a silver surfaceThe Journal of Chemical Physics, 1980
- Luminescence and nonradiative energy transfer to surfacesPhysical Review B, 1980
- Molecular Fluorescence and Energy Transfer Near InterfacesAdvances in Chemical Physics, 1978
- Long range vibrational energy transfer from ND and NH(A 3Π) to CO and N2 in solid ArThe Journal of Chemical Physics, 1976
- Zur Variation von Lumineszens-LebensdauernAnnalen der Physik, 1973
- Zur Variation von Lumineszens‐LebensdauernAnnalen der Physik, 1973
- Optical Constants of the Noble MetalsPhysical Review B, 1972