Scandium triflate-catalyzed Strecker-type reactions of aldehydes, amines and tributyltin cyanide in both organic and aqueous solutions. Achievement of complete recovery of the tin compounds toward environmentally-friendly chemical processes
- 1 January 1998
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 9,p. 981-982
- https://doi.org/10.1039/a801464g
Abstract
Scandium triflate (CF3SO3 –)-catalyzed Strecker-type reactions were successfully carried out by simply mixing aldehydes, amines and tributyltin cyanide at room temperature, to afford α-amino nitriles in high yields. The reactions proceeded smoothly in both organic and aqueous solutions, and complete recovery of the tin materials has been achieved.Keywords
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