Acylchlorination and Related Reactions of Fluoroethenes Using AlCl3 and FeCl3
- 1 March 1981
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 54 (3) , 832-835
- https://doi.org/10.1246/bcsj.54.832
Abstract
Acylchlorination of mono-, 1,1-di-, and trifluoroethenes with carboxylic acid chlorides using AlCl3 and FeCl3 as a Lewis acid was investigated. In AlCl3-catalyzed reactions, fluorine-chlorine exchange reaction always occurred in part, while in FeCl3-catalyzed reactions Claisen-type condensation giving β-diketones was observed. Preparations of 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, and 2-chloro-1,2,2-trifluoroethyl ketones are given.Keywords
This publication has 3 references indexed in Scilit:
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- Aromatic Substitution. XV.1 Ferric Chloride Catalyzed Bromination of Halobenzenes in Nitromethane SolutionJournal of the American Chemical Society, 1964
- A Study of Acid Catalysis in Ketone AcylationsJournal of the American Chemical Society, 1953