Long-Range Self-Assembly of a Polyunsaturated Linear Organosilane at the n-Tetradecane/Au(111) Interface Studied by STM
- 1 August 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 124 (34) , 9998-9999
- https://doi.org/10.1021/ja027002z
Abstract
We report on the formation of self-assembled monolayers of 13-(trimethylsilyl)-1-tridecene-6,12-diyne [C13H17-Si(CH3)3], an organosilane derivative with a linear polyunsaturated chain, on Au(111) substrates. Molecular resolution STM images recorded at the liquid-solid interface between gold and tetradecane reveal a long-range and densely packed hexagonal lattice with a ( radical3 x radical3)R30 degrees -like structure commensurate against gold adlattice.Keywords
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