Carbonyl insertion at chloro(alkyl or aryl)(methyldiphenylphosphine)-carbonylplatinum: critical effects of stereochemistry and the nature of the alkyl or aryl group
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 819-820
- https://doi.org/10.1039/c39780000819
Abstract
The chloride-bridged acyl complexes [Pt2(µ-Cl)2(COR)2(PMePh2)2] equilibrate with one isomer of [PtClR(CO)(PMePh2)] in solution, and the equilibrium position is critically dependent on the nature of R.Keywords
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