Abstract
Irradiation effects of uranium containing iron (II, III) metaphosphate glasses with a reactor were investigated by Mössbauer spectroscopy. The irradiation induced changes of the oxidation state of iron were attributed to holes and electrons created by γ rays. On the other hand, the changes in Moössbauer parameters with irradiation time and uranium content were ascribed to vacancy association phenomena which are closely related with fission track formation in the glasses

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