Proton Tunneling in Acetic Acid Dimers
- 1 April 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 46 (7) , 2735-2740
- https://doi.org/10.1063/1.1841105
Abstract
The group theory of nonrigid systems is applied to determine the effects of proton tunneling in the vibrational spectrum of the dimer. It is shown that the doublet observed in the far‐infrared spectrum of the vapor is unlikely to be due to proton tunneling. This conclusion is confirmed by the observation that the doublet remains in the spectrum of (CH3COOD)2.Keywords
This publication has 15 references indexed in Scilit:
- Far infrared spectra of dimeric and crystalline formic and acetic acidsSpectrochimica Acta, 1966
- A GROUP-THEORETICAL TREATMENT OF ELECTRONIC, VIBRATIONAL, TORSIONAL, AND ROTATIONAL MOTIONS IN THE DIMETHYLACETYLENE MOLECULECanadian Journal of Physics, 1964
- The solution spectrum of CF4Spectrochimica Acta, 1961
- Far Infrared Spectra of Gaseous Formic Acid and Aceti AcidNippon kagaku zassi, 1960
- Far Infrared Spectrum of Gaseous Formic AcidBulletin of the Chemical Society of Japan, 1959
- Low Frequency Vibrations, Polarizability and Entropy of Carboxylic Acid Dimers1Journal of the American Chemical Society, 1959
- An Electron Diffraction Investigation of the Monomers and Dimers of Formic, Acetic and Trifluoroacetic Acids and the Dimer of Deuterium Acetate1Journal of the American Chemical Society, 1944
- Anomalous Scattering of Neutrons by HeliumPhysical Review B, 1940
- The Envelopes of Infrared Absorption BandsPhysical Review B, 1933
- Infrared Bands of Slightly Asymmetric MoleculesPhysical Review B, 1931