Distribution of Nitric Acid Vapor in the Stratosphere as Determined from Infrared Atmospheric Emission Data

Abstract
Infrared emission spectra were measured in the stratosphere at various altitudes and from various zenith angles by means of a balloon-borne Czerny-Turner spectrometer. The equation of radiative transfer was applied to the radiances measured at 11.2μ to yield a concentration profile of HNO3 vapor. The resulting HNO3 concentration profile was characterized by a negligible concentration below 14 km, a maximum concentration of ∼(1.5±0.5)×1010 molecules cm−3 at ∼(19±5) km, and a diminishing concentration above these altitudes. Abstract Infrared emission spectra were measured in the stratosphere at various altitudes and from various zenith angles by means of a balloon-borne Czerny-Turner spectrometer. The equation of radiative transfer was applied to the radiances measured at 11.2μ to yield a concentration profile of HNO3 vapor. The resulting HNO3 concentration profile was characterized by a negligible concentration below 14 km, a maximum concentration of ∼(1.5±0.5)×1010 molecules cm−3 at ∼(19±5) km, and a diminishing concentration above these altitudes.