Retention of Structural Cores in the Synthesis of High-Nuclearity Polyoxoalkoxomolybdate Clusters Encapsulating [Na(H2O)3]+ and [MoO3] Moieties. Hydrothermal Syntheses and Structures of (NH4)7[NaH12Mo16O52]·4H2O and (Me3NH)4K2[H14Mo16O52]·8H2O and Their Structural Relationships to the Class of Superclusters [XHnMo42O109{(OCH2)3CR}7]m- (X = Na(H2O)3+: n = 13, m = 9; n = 15, m = 7. X = MoO3: n = 14, m = 9; n = 13, m = 10)
- 1 January 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 35 (7) , 1880-1901
- https://doi.org/10.1021/ic9508841
Abstract
No abstract availableKeywords
This publication has 48 references indexed in Scilit:
- (H3N(CH2)6NH3)4 [W18P2O62] · 3H2O, a Microporous Solid from Dawson Anions and 1,6‐DiaminohexaneAngewandte Chemie International Edition in English, 1995
- Hydrothermal Synthesis and Crystal and Molecular Structure of a Neutral Polyoxoalkoxyvanadium(IV) Cluster with a Hexadecametalate Core, [V16O20{(OCH2)3CCH2OH}8(H2O)4].cntdot.3H2OJournal of the American Chemical Society, 1994
- Supramolecular chemistry: molecular aggregates of closo-B10H102- with [12]mercuracarborand-4Journal of the American Chemical Society, 1993
- A novel polyoxo molybdenum(V) organophosphonate anion having a sandwich structure: synthesis and crystal structure of [N(C2H5)4]2Na3(H3O)4{Na[Mo6O15(O3PC6H5)(HO3PC6H5)3]2}..apprx.14H2OInorganic Chemistry, 1993
- New Directions in Polyvanadate Chemistry: From Cages and Clusters to Baskets, Belts, Bowls, and BarrelsAngewandte Chemie International Edition in English, 1992
- Inclusion of Metal Ions within a Tin—Oxygen Cage Stabilized by Organic Residues: Crystal Structure of [(iPrSn)12O4(OH)24][Ag7I11] · NaCl · H2O · 10DMSOAngewandte Chemie International Edition in English, 1991
- Solution structure elucidation of early transition metal polyoxoalkoxides using oxygen-17 NMR spectroscopyJournal of the American Chemical Society, 1991
- Synthesis of a new one-dimensional sodium molybdenum phosphate polymer: structure of [(H3O)2NaMo6P4O24(OH)7]2-Inorganic Chemistry, 1989
- Unusually rapid homolysis of the cobalt-carbon bond in a macrocyclic benzylcobalt complexInorganic Chemistry, 1987
- Structural studies of Mo(VI) coordination chemistry crystal and molecular structure of trispotassium [cis-trioxo(nitrilotriacetato)molybdate(VI)] monohydrateJournal of Chemical Crystallography, 1976