Evidence for the 1,3-silyl shift equilibrium between the CO- and CTe-bonded isomers of a stable trimethylsilyl tellurocarboxylate
- 1 January 1987
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 820-821
- https://doi.org/10.1039/c39870000820
Abstract
The reaction of bis(trimethylsilyl) telluride with equimolar amounts of pivaloyl chloride affords ButCOTeSiMe3, which exists as a mixture of CO- and CTe-bonded isomers related by a 1,3-silyl shift equilibrium (multinuclear n.m.r. spectroscopic evidence).Keywords
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