PALLADIUM OR RUTHENIUM CATALYZED REACTION OF α-HALO KETONES WITH TRIBUTYLTIN ENOLATES: PREPARATION OF UNSYMMETRICAL 1,4-DIKETONES
- 5 July 1984
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 13 (7) , 1221-1224
- https://doi.org/10.1246/cl.1984.1221
Abstract
Palladium or ruthenium catalyzed cross-coupling of α-halo ketones with tributyltin enolates gave unsymmetrical 1,4-diketones, The method was applied to the dihydrojasmone synthesis.This publication has 16 references indexed in Scilit:
- Synthesis of 1,4-diketones by oxidative coupling of ketone enolates with copper(II) chlorideJournal of the American Chemical Society, 1977
- New 1,4-diketone synthesis using nitroolefins and trimethylsilyl enol ethers. A convenient regiospecific route to cyclopentenonesJournal of the American Chemical Society, 1976
- Generalized syntheses of .gamma.-diketones. I. Addition of dimetalloacetylides to aldehydes. II. Dialkylation of bisdithianesThe Journal of Organic Chemistry, 1975
- Synthesis of 1,4-diketones by the reaction of silyl enol ether with silver oxide. Regiospecific formation of silver(I) enolate intermediatesJournal of the American Chemical Society, 1975
- Synthesis of 1,4-diketones by reductive coupling of .alpha.,.alpha.'-dibromo ketonesJournal of the American Chemical Society, 1974
- New method for the conversion of nitro groups into carbonylsThe Journal of Organic Chemistry, 1973
- Convenient synthesis of 1,4-diketones. Application to the synthesis of dihydrojasmoneJournal of the American Chemical Society, 1972
- 1,4 Addition of acyl groups to conjugated enonesJournal of the American Chemical Society, 1969
- The development of the chemistry of furans, 1952-1963Published by Elsevier ,1967
- Recent Advances in the Chemistry of Pyrrole.Chemical Reviews, 1963