The introduction of elastomeric behavior into polycarboranylenesiloxane SiB‐1 polymers from the closo‐carborane C2B5H7
- 1 October 1970
- journal article
- research article
- Published by Wiley in Journal of Applied Polymer Science
- Vol. 14 (10) , 2525-2536
- https://doi.org/10.1002/app.1970.070141008
Abstract
The copolymerization of a small amount of the larger (C2B8 and C2B10) carboranes with the smaller C2B5 carborane resulted in the formation of an elastomeric SiB‐1 carboranesiloxane, a polymer hitherto prepared only in crystalline form. Although the elastomeric behavior of the uncured SiB‐1 copolymer decreased with time, curing stabilized the rubber by inhibiting crystallization.Keywords
This publication has 5 references indexed in Scilit:
- Direct synthesis of closo-carboranesInorganic Chemistry, 1970
- Poly-m-Carboranesiloxanes as Thermoresistant ElastomersRubber Chemistry and Technology, 1966
- A new series of organoboranes. VII. The preparation of poly‐m‐carboranylenesiloxanesJournal of Polymer Science Part A-1: Polymer Chemistry, 1966
- A New Series of Organoboranes. I. Carboranes from the Reaction of Decaborane with Acetylenic CompoundsInorganic Chemistry, 1963
- Polymer composition versus low‐temperature characteristics of polysiloxane elastomersJournal of Applied Polymer Science, 1959