The rate of collisional quenching of N2O+ (B 2Σ), N+2 (B 2Σ), O+2 (b 4Σ), O+ (3d), O (3p), Ar+ (4p′), Ar (4p,4p′) at the temperature ≤200 K
- 15 February 1995
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 102 (7) , 2792-2801
- https://doi.org/10.1063/1.468655
Abstract
Rate constants of collisional quenching of the states N2O+ (B 2Σ+u), N+2 (B 2Σ+u), O+2 (b 4Σ−u), O i (3p 5P), O ii (3d 4F), Ar ii (4p′ 2F0) in their parent gases and the states Ar i (4p,4p′[1/2]) in oxygen have been measured by studying Stern–Volmer dependencies in the temperature range from 20 to 200 K. Radiating states were excited by the electron beam. A flow on free jet axis was used as a gas target. Negative dependencies of rate constants on temperature which were obtained are consistent with the available experimental data on rate of internal energy and charge transfer at low energy collisions.Keywords
This publication has 44 references indexed in Scilit:
- Temperature dependence of the quenching of O(1S) by simple inorganic moleculesThe Journal of Chemical Physics, 1993
- Charge-transfer chemistry of argon(1+) (2P3/2) and krypton(1+) (2P3/2) at very low collision energiesThe Journal of Physical Chemistry, 1992
- Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement III. IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric ChemistryJournal of Physical and Chemical Reference Data, 1989
- Collisional quenching of singlet molecular oxygen, O2(a 1? g ) and O2(b 1? + g ), by ammonia at high temperaturesJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1984
- Radiative-lifetime measurements of the 4p^5P, 4p^3P, and 4d^5D^∘ multiplets of O iJournal of the Optical Society of America, 1981
- Lifetimes of Some Levels in Neutral Carbon, Nitrogen and OxygenPhysica Scripta, 1978
- Collisional deactivation of excited ions of carbon dioxide and nitrous oxideThe Journal of Chemical Physics, 1973
- Quenching rates for N + 2 , N2O+, and CO + 2 emission bands excited by 58.4 nm irradiation of N2, N2O, and CO2Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1972
- Absolute Fluorescence Yields of 3914-Å Photons fromand Air Excited by Relativistic ElectronsPhysical Review A, 1970
- De-excitation of Electronically Excited Sodium by NitrogenThe Journal of Chemical Physics, 1969