Formation of benzoylsilanes from the reaction of organosilylcobalt tetracarbonyl derivatives with phenyl-lithium
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 73-74
- https://doi.org/10.1039/c39770000073
Abstract
Treatment of organosilylcobaltcarbonyl complexes [R3SiCo(CO)4] with phenyl-lithium gives benzoylsilanes R3SiCOPh, with retention of configuration at silicon; an intermediate adduct [R3SiCo(CO)3COPh]– Li+ is probably formed and the salt [(α-Np)PhMeSi*Co(CO)3COPh]– N+(PPh3)2(where α-Np =α-naphthyl) has been isolated.Keywords
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