A novel Rh–B σ bond. Crystal structure of [N(CH3)4][RhCl{7,8-µ-S(CH2CH2)S-C2B9H10}{σ-7,8-µ-S(CH2CH2)S-C2B9H9}]
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 192-193
- https://doi.org/10.1039/c39910000192
Abstract
The complex [N(CH3)4][RhCl{7,8-µ-S(CH2CH2)S–C2B9H10}{σ-7,8-µ-S(CH2CH2)S–C2B9H9}] is an octahedral Rh(III) complex; the sixth coordination site is occupied by a σ-bond B–Rh in this first example of B(3)–Rh coordination.Keywords
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