Asymmetric synthesis of two diastereomeric P-chiral diphosphine ligands containing a pair of dissimilar asymmetric phosphorus donor atoms
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 24,p. 2397-2398
- https://doi.org/10.1039/a706982k
Abstract
Two diastereoisomeric P-chiral diphosphine ligands, each containing a pair of dissimilar phosphorus donor atoms, have been prepared efficiently in their optically pure forms from a chiral organopalladium complex-promoted asymmetric Diels–Alder reaction between 1-phenyl-3,4-dimethylphosphole and methylphenylvinylphosphine.Keywords
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