New polyphosphorus ligands: addition reactions of 1,1-bisdiphenylphosphinoethene

Abstract
The reactivity of the double bond adjacent to the geminal diphenylphosphino groups of (Ph2P)2CCH2 facilitates the addition of species with one or more P–H bonds to provide a convenient high-yielding route to a range of new poly- and ambi-dentate ligands which can form a wide variety of different types of transition metal complex.

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