Ion Association of LiI inp-Dioxane—Water Mixtures. I. Conductance Measurements
- 15 December 1966
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 45 (12) , 4716-4718
- https://doi.org/10.1063/1.1727561
Abstract
The conductance of LiI has been measured in p‐dioxane—water mixtures at 25° over the composition range 0%—95% dioxane. The data were analyzed using the Fuoss—Onsager theory to give Λ0, aJ, and KA parameters. Although aJ remains constant over the whole composition range, the Walden product decreases monotonically. Both the Stokes radius and the association constant show markedly different behavior in the range over 80% dioxane.Keywords
This publication has 12 references indexed in Scilit:
- Microwave Absorption and Molecular Structure in Liquids. LXVI. The Dielectric Relaxation of the Water—Dioxane System and the Structure of WaterThe Journal of Chemical Physics, 1965
- The Kinetics of Ion Association in Manganese Sulfate Solutions. I. Results in Water, Dioxane-Water Mixtures, and Methanol-Water Mixtures at 25°The Journal of Physical Chemistry, 1965
- Conductance of the Alkali Halides. VIII. Lithium-7 Chloride in Dioxane—Water Mixtures at 25°1The Journal of Physical Chemistry, 1964
- The Conductance of Symmetrical Electrolytes.1a IV. Hydrodynamic and Osmotic Terms in the Relaxation FieldThe Journal of Physical Chemistry, 1964
- ION ASSOCIATION IN POLYVALENT SYMMETRICAL ELECTROLYTES. V. THE CONDUCTANCE OF SOME ALKALINE EARTH m-BENZENEDISULFONATES IN WATER AT 25°The Journal of Physical Chemistry, 1963
- Specific Solvation of Electrolytes in Binary Solvent SystemsJournal of the American Chemical Society, 1963
- The ultra‐violet absorption spectrum of iodides in dioxan‐water mixturesRecueil des Travaux Chimiques des Pays-Bas, 1962
- On the Electrical Conductance of KCl in Various Solvent Mixtures at 25 degrees C. Test of the Theoretical Equations.Acta Chemica Scandinavica, 1962
- Conductance of Dilute Solutions of 1-1 Electrolytes1Journal of the American Chemical Society, 1959
- Ionic Association. III. The Equilibrium between Ion Pairs and Free IonsJournal of the American Chemical Society, 1958