First-order phase transition between orthorhombic phases in YBa2Cu3Oz

Abstract
We investigate the effects of elastic interactions and the associated orthorhombic distortion on the structural phase transitions in YBa2 Cu3 Oz. Starting from a two-dimensional Ising model previously demonstrated to describe accurately the high-temperature phase boundaries, we show by means of Landau theory that the square-rectangular symmetry breaking may lead to a first-order transition between the orthorhombic single- and double-cell phases at low temperatures. This explains experimental observations of phase separation between orthorhombic phases, while retaining the simplicity and predictive power of the original model.