First-order phase transition between orthorhombic phases in
- 1 September 1993
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 48 (9) , 6588-6592
- https://doi.org/10.1103/physrevb.48.6588
Abstract
We investigate the effects of elastic interactions and the associated orthorhombic distortion on the structural phase transitions in . Starting from a two-dimensional Ising model previously demonstrated to describe accurately the high-temperature phase boundaries, we show by means of Landau theory that the square-rectangular symmetry breaking may lead to a first-order transition between the orthorhombic single- and double-cell phases at low temperatures. This explains experimental observations of phase separation between orthorhombic phases, while retaining the simplicity and predictive power of the original model.
Keywords
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