Synthesis and characterization of a new family of luminescent cis-(4,4'-X2-5,5'-Y2-2,2'-bipyridine)2Os(CO)Cl(PF6) complexes (X = NEt2, OMe, Me, H, Cl, Y = H; X = H, Y = Me; X = Y = Me): control of excited-state properties by bipyridyl substituents