Carbon–carbon bond cleavage via oxidative addition: reaction of tetrakis(triphenylphosphine)platinum(0) with 1,1,1-tricyanoethane
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1663-1666
- https://doi.org/10.1039/j19710001663
Abstract
The reaction of [Pt(PPh3)4] with MeC(CN)3 in benzene yields the complex [Pt(PPh3)2(CN)(CMe(CN)2)], a rare example of an oxidative addition reaction involving carbon–carbon cleavage.Keywords
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