Escape over barriers in almost integrable systems
- 8 February 1988
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 60 (6) , 473-476
- https://doi.org/10.1103/physrevlett.60.473
Abstract
Whenever the escaping entity and the thermal reservoir in contact with it move at comparable rates, escape must be viewed as due to diffusion in the space of the action variables. For almost integrable systems, the effective barrier height is argued to exceed substantially the potential-energy barrier of conventional theory, at least in the common case in which the potential barrier arises from terms in the Hamiltonian responsible for the nonintegrability, and to the extent that the usual quasiperturbative treatment of almost integrable systems is applicable at energies of order of the barrier.Keywords
This publication has 7 references indexed in Scilit:
- Brownian motion in a field of force and the diffusion model of chemical reactionsPublished by Elsevier ,2004
- Bottlenecks to unimolecular reactions and an alternative form for classical RRKM theoryThe Journal of Physical Chemistry, 1986
- Unimolecular reactions and phase space bottlenecksThe Journal of Chemical Physics, 1986
- Validity of Brownian-motion theory of activated processes: Diffusion in solidsPhysical Review B, 1982
- A universal instability of many-dimensional oscillator systemsPhysics Reports, 1979
- Resonance Broadening in Mode CouplingPhysical Review Letters, 1971
- Calculation of the Rate of Elementary Association ReactionsThe Journal of Chemical Physics, 1937