Synthesis of enantiomeric pureCis-dichloroplatinum(II) amino acid complexes
- 1 December 1982
- journal article
- Published by Springer Nature in Biological Trace Element Research
- Vol. 4 (4) , 331-335
- https://doi.org/10.1007/bf02786546
Abstract
The reaction of potassium tetrachloroplatinate(II) with six representative sulfurcontaining amino acids, namely,d- andl-cysteine,d- andl-methionine and its methyl ester hydrochloride gives the corresponding enantiomerically purecis-dichloroplatinum(II) complexes. This represents the first reported series of well-characterized enantiomerically pure platinum(II) complexes for bothd- andl-amino acids. The spectroscopic properties, including IR,1H-NMR, and13C NMR, of these complexes and their configuration are discussed.Keywords
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