Nucleophilic Displacement of the Nitro Group in n6-Nitroarene-n5-cyclopentadienyliron Hexafluorophosphates
- 6 December 1985
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 15 (9) , 1237-1245
- https://doi.org/10.1080/00945718508059404
Abstract
The nitro group in n6-nitrobenzene or o-, m-, or p-nitrotoluene-n5 -cyclopentadienyliron hexaflurophosphate (I, II, III or IV, respectively) was shown to undergo readily nucleophilic displacement reactions when treated with an O, S or N containing nucleophile. The products obtained include the CpFe complexes of substituted arenes from reactions of I, II, III or IV with CH3OH, C2OH or p-CH3C6H4SH, all carried out in the presence of K2CO3, or with pyrrolidine.Keywords
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