Photochemistry of the supercomplex obtained on complexation of the hexacyanocobaltate(III) anion by a polyammonium macrocyclic receptor
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 555-556
- https://doi.org/10.1039/c39840000555
Abstract
Enclosure of Co(CN)6 3–into a polyammoniumm macrocyclic ligand partially hinders the CN– photoaquation reaction, showing that it may be possible to control and orient the ligand photosubstitution reactions of transition metal complexes by using appropriate receptor molecules.Keywords
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