Platinum(0) activation of rhenium polyhydride complexes: synthesis and X-ray crystal structure of the hydrido-ethyene complelx [ReH3(C2H4)2(PPhPri 2)2]
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1663-1664
- https://doi.org/10.1039/c39840001663
Abstract
In the presence of [Pt(PPhBut 2)2] or [Pt(C2H4)2(PPhPri 2)] and ethylene (1 atm), [ReH7(PR3)2][PR3= PPhPri 2(1a); P(cyclopently)3(1b)] reacts to give [ReH3(c2H4)2(PR3)2](2), which affords [ReH5(C2H4)(PR3)2](3) on exposure to H2(1 atm).Keywords
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