Molecular polarisability. The apparent conformations of acetic anhydride and diacetyl sulphide as solutes in benzene or carbon tetrachloride
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic
- p. 338-341
- https://doi.org/10.1039/j29710000338
Abstract
The apparent dipole moments and molar Kerr constants found for Ac2O and Ac2S as solutes in carbon tetrachloride or benzene are reconcilable with non-planar conformations derivable from the s-cis models by rotating each acetyl group within the range 130–140° in a clockwise sense (looking from the central atom towards Ac).Keywords
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