Absorption Coefficients of Oxygen in the 1060–580-Å Wavelength Region
- 15 January 1964
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 40 (2) , 356-365
- https://doi.org/10.1063/1.1725119
Abstract
Absorption coefficients of oxygen have been measured in the 1060–580‐Å wavelength region using a continuum background at a bandwidth of 0.5 Å. The background light source is a repetitive discharge through helium which produces the Hopfield continuum. Absorption bands and underlying dissociation and ionization continua are observed throughout this wavelength region. The continuum rises linearly from ≲20 cm—1 at the first ionization threshold (1026.7 Å), to about 300 cm—1 at 840 Å where the continuum begins to rise more sharply. Toward shorter wavelengths, there are three maxima in the continuum at about 800, 720, and 610 Å with approximate k values of 850, 850, and 1000 cm—1, respectively. The absorption bands appear diffuse, probably due to pre‐ionization, and maximum k values of up to 1700 cm—1 are found. Dissociation and ionization processes responsible for the continua are discussed, and comparison is made with previous absorption coefficient measurements.Keywords
This publication has 20 references indexed in Scilit:
- Fluorescence and Pre-Ionization in Nitrogen Excited by Vacuum Ultraviolet RadiationThe Journal of Chemical Physics, 1963
- Recent improvements in rare gas continua in the vacuum ultraviolet regionJournal of Quantitative Spectroscopy and Radiative Transfer, 1962
- Ionization potentials of some moleculesJournal of Quantitative Spectroscopy and Radiative Transfer, 1962
- Solar Emission Lines in the Extreme Ultraviolet.The Astrophysical Journal, 1959
- Photodissociation and Photoionization of Oxygen (O_2) as Inferred from Measured Absorption CoefficientsJournal of the Optical Society of America, 1955
- Oxygen Gas Continuous Absorption in the Extreme Ultraviolet*Journal of the Optical Society of America, 1955
- Photoionization Efficiencies and Cross Sections in , , C, A, O, , and CPhysical Review B, 1955
- Absorption Coefficients of Oxygen in the Vacuum UltravioletJournal of the Optical Society of America, 1952
- New O2+Second Negative Bands: a Note on O3and O II Emission SpectraProceedings of the Physical Society. Section A, 1950
- Rotational analysis of the first negative band spectrum of oxygenPhilosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, 1938