Unusual stereoselectivity in the reduction of bicyclo[3.3.0]oct-2-en-8-one by Thermoanaerobiumbrockii alcohol dehydrogenase
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1330-1332
- https://doi.org/10.1039/c39910001330
Abstract
The Thermoanaerobium brockii alcohol dehydrogenase (TBADH) catalysed reduction of the racemic bicyclic ketone 5 gives epimeric alcohols derived from the same enantiomeric series, the reduction is enantioselective but not diastereoselective, an unusual result for a single enzyme.Keywords
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