Novel approach to the high-yield synthesis of tertiary alcohols using organoboranes
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 863a
- https://doi.org/10.1039/c3974000863a
Abstract
Trialkylmethanols (R1 2R2COH) are produced in essentially quantitative yields by treatment of trialkylboranes successively in the same vessel with 1-lithio-1,1-bis(phenylthio)alkene (–30 to 20°), HgCl2(–78 to 0°) and alkaline hydrogen peroxide (20°).Keywords
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