A new method for the synthesis of furan derivatives: I. Introduction
- 1 January 1948
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 67 (7) , 539-544
- https://doi.org/10.1002/recl.19480670705
Abstract
A new method for the synthesis of furan derivatives is outlined. By the action of a mixture of concentrated sulphuric acid and acetic anhydride in the molecular ratio of 1:2 on αβ‐ or β γ‐unsaturated ketones, having a branching of the carbon skeleton in the β‐position, δ‐sultones with two conjugated double bonds in the hetero‐ring are obtained. On pyrolysis these δ‐sultones yield sulphur dioxide and a furan derivative.Keywords
This publication has 2 references indexed in Scilit:
- Über Sulfonsäuren von Terpenen und Sesquiterpenen, I. Mitteil.: Der Cyclo‐pulegenol‐sulfonsäure‐ester und sein Übergang in MenthofuranBerichte der deutschen chemischen Gesellschaft (A and B Series), 1937
- IV. Fachgruppe für medizinisch‐pharmazeutische ChemieAngewandte Chemie, 1934