Palladium(II) complexes containing ‘mixed’ nitrogen–arsenic polydentate ligands
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 175-179
- https://doi.org/10.1039/dt9730000175
Abstract
Palladium(II) dihalides (Cl, Br, or I) react with R2NC2H4AsPh2 and [R2NC2H4]2AsPh, where R = H, Me, and Et, to form a series of four-co-ordinate, square planar complexes of stoicheiometry PdX2L, when X = Cl, Br, and I and L represents any one of the aforementioned ligands. In addition, the S-bonded thiocyanate complexes, Pd(SCN)2L, were prepared for all three bidentate ligands. The explanations for the isolation of only the S-bonded isomer and the inability to prepare five-co-ordinate complexes are discussed.Keywords
This publication has 0 references indexed in Scilit: