Novel photoreactions of styrylcyclopropanes via photo-induced electron transfer
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1665-1667
- https://doi.org/10.1039/c39840001665
Abstract
9,10-Dicyanoathracene-sensitized photoreaction of styrylcyclopropanes in the presence of Cu(BF4)2 in MeCN–MeOH gives α-cyclopropyl nenzyl ketones as major products, which are produced via a two-electron oxidation of styrylcyclopropanes followed by a 1,2-migration of the cyclopropyl group.Keywords
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