Diastereoselective control in the addition of Grignard reagents to ketones using a 1,3-dithiane 1-oxide auxiliary
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 6,p. 1158-1160
- https://doi.org/10.1039/p19890001158
Abstract
2-Acyl-1,3-dithiane 1-oxides undergo diastereoselective addition of Grignard reagents; very high selectivities have been observed under certain reaction conditions.Keywords
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