Unstable intermediates. Part XXXIV. Solvated electrons: a model for the spin-paired species in liquid ammonia

1 January 1966

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 13-16
https://doi.org/10.1039/j19660000013

Abstract

It is suggested that of the current models representing the diamagnetic species in metal–ammonia solutions, the (e₂ ^2–)_solv. or F′ model is the most satisfactory. Evidence for this postulate is drawn from a wide range of experimental data including optical studies, electron spin resonance and nuclear magnetic resonance spectroscopy, and from results for solutions of europium in liquid ammonia.

Keywords

MODEL
SPIN
RESONANCE
UNSTABLE
EXPERIMENTAL
SOLVATED
DIAMAGNETIC
POSTULATE
EUROPIUM
OPTICAL

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