Reactions of O(1D) with atmospheric molecules
- 1 March 1975
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 62 (5) , 1893-1898
- https://doi.org/10.1063/1.430675
Abstract
A statistical model of chemical reaction is applied to collisions of O(1D) atoms with the molecules H2, N2, CO, CO2, N2O, O3, and H2O. Rate constants for reaction and deactivation are computed over the temperature range 100−2100°K. Competition among various product channels is investigated. In most cases quantitative agreement with experiment is achieved.Keywords
This publication has 13 references indexed in Scilit:
- The Effect of the Excess Kinetic Energy of the O(1D) Atoms from the Flash Photolysis of N2O on their Reaction with N2OCanadian Journal of Chemistry, 1974
- Survey of Photochemical and Rate Data for Twenty-eight Reactions of Interest in Atmospheric ChemistryJournal of Physical and Chemical Reference Data, 1973
- Kinetic investigation of electronically excited oxygen atoms, O(21D2), by time-resolved attenuation of atomic resonance radiation in the vacuum ultra-violet. Part 2.—Collisional quenching by the atmospheric gases N2, O2, CO, CO2, H2O and O3.Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1973
- Relative rate of reaction of O(1D2) with H2OChemical Physics Letters, 1971
- Competitive Reactions of the Excited Oxygen Atoms, O(1D)*Journal of the American Chemical Society, 1969
- Reaction of O(1D) with H2 and the Reactions of H and OH with OzoneThe Journal of Chemical Physics, 1967
- The production, deactivation and chemical reactions of atomsPlanetary and Space Science, 1967
- Quenching of metastable states of atomic and molecular oxygen and nitrogenReviews of Geophysics, 1966
- Intensities of Forbidden Lines of Atoms in pn-configurationJournal of the Physics Society Japan, 1952
- The Van Der Waals Forces in GasesPhysical Review B, 1931