Photodissociation Spectrum of C $O_{3}^{-}$ : Evidence for a Bound Excited State

30 June 1975

journal article
research article
Published by American Physical Society (APS) in Physical Review Letters

Vol. 34 (26) , 1603-1606
https://doi.org/10.1103/physrevlett.34.1603

Abstract

The photodissociation cross section for

C {O_{3}}^{-} + h ν \to C O_{2} + O^{-}

has been measured from 6400 to 5650 Å using a drift-tube mass spectrometer and a continuously tunable dye laser. The cross section has very detailed structure, which is interpreted as reflecting the vibrational levels of a bound, predissociating state of C

O_{3}^{-}

Keywords

This publication has 10 references indexed in Scilit:

Matrix-isolation study of the vibrational spectrum and structure of the CO3− radical anion
Journal of Molecular Spectroscopy, 1974
Photodissociation reaction CO−3
Chemical Physics Letters, 1974
Autodetaching States in $I^{-}$
Physical Review Letters, 1974
Application of Scattering Theory to the Calculation of Alkali Negative-Ion Bound States
Physical Review Letters, 1974
Resonances in Alkali Negative-Ion Photodetachment and Electron Affinities of the Corresponding Neutrals
Physical Review Letters, 1974
Direct Observation of an Autodetaching State of $I^{-}$
Physical Review Letters, 1973
Vibrational and electronic spectra of the O3− anion isolated in an argon matrix
Journal of Molecular Spectroscopy, 1972
Two photon photodetachment spectroscopy: The C−22σ states
Chemical Physics Letters, 1972
Photodetachment of $O_{2}^{-}$
Physical Review B, 1958
Photodetachment Cross Section and the Electron Affinity of Atomic Oxygen
Physical Review B, 1958

Photodissociation Spectrum of CO3−: Evidence for a Bound Excited State

Abstract

Keywords

Photodissociation Spectrum of C $O_{3}^{-}$ : Evidence for a Bound Excited State