Absolute configuration and biosynthesis of the austalides, meroterpenoid metabolites of Aspergillus ustus: mode of cyclisation of the farnesyl moiety
- 1 January 1989
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 393-394
- https://doi.org/10.1039/c39890000393
Abstract
A study of the fate of the hydrogen atoms in the biosynthesis of austalide D using both (13C,2H)- and 2H-labelled mevalonolactones established, in conjunction with absolute configuration as determined by an X-ray crystallographic study, the stereochemical course of cyclisation of the farnesyl-derived moiety.Keywords
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