First total synthesis of the marine illudalane sesquiterpenoid alcyopterosin EElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b2/b209573d/

Abstract
The first synthesis of the marine illudalane sesquiterpenoid alcyopterosin E was accomplished through a concise ABC ring-formation strategy using a rhodium(I)-catalysed intramolecular alkyne cyclotrimerisation as key connection.

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