Theoretical optical rotation of oriented hexahelicene
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 71, 293-300
- https://doi.org/10.1039/f29757100293
Abstract
The three specific rotation components of an oriented hexahelicene molecule are calculated by extending the Kirkwood dynamic-coupling theory to include electric dipole-electric quadrupole optical activity. All three components are found to have the same sign and similar magnitudes.Keywords
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