The mechanism of the protodesilylation of allylsilanes and vinylsilanes
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1421-1423
- https://doi.org/10.1039/p19810001421
Abstract
The protodesilylation of either 1-dimethyl(phenyl)silyl-3-trimethylsilypropene (15) or its isomer, 1-trimethylsilyl-3-dimethyl(phenyl)silylpropene (16), gave the same, ca. 4 : 1, mixture of allylsilanes, 3-dimethyl(phenyl)silylpropene (18) and 3-trimethylsilylpropene (19), showing that a cationic intermediate (17) is involved in both reactions.Keywords
This publication has 0 references indexed in Scilit: