REACTIONS OF NAD+-MODEL COMPOUNDS WITH BASE. THE REVISED STRUCTURE OF DITTMER’S TRIMER

Abstract
The structure of the cyclic trimer obtained by the reaction of N-benzylnicotinamide cation with base was established. A plausible mechanism involves the removal of the amide hydrogen with base, the attack of the amide anion at C-4 of another pyridinium ion, and the formation of a 12-membered ring.

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