The mechanism of formation of propionaldehyde and π-allylplatinum(II) complexes from allyl alcohol and diallyl ether with cationic platinum(II) hydrides
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 150-151
- https://doi.org/10.1039/c39720000150
Abstract
Migration of the CC bond and chelate ring formation occur in the insertion reactions of allylic acetates with cationic platinum(II) hydrides; similar behaviour explains the formation of π-allylplatinum(II) complexes and propionaldehyde from reactions of allyl alcohol or diallyl ether with such cationic hydrides.Keywords
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