Synthesis and X-ray crystal structure of [Mo(CO2)2(PMe3)3(CNPri)]: the first structurally characterized bis(carbon dioxide) adduct of a transition metal
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1326-1327
- https://doi.org/10.1039/c39840001326
Abstract
The reaction of trans-[Mo(CO2)2(PMe3)4] with isocyanides yields the new bis(carbon dioxide) complexes trans, mer-[Mo(CO2)2(CNR)(PMe3)3], (R = Me, Pri, or But); the structure of the isopropyl derivative [Mo(CO2)2(CNPri)(PMe3)3] has been determined by X-ray crystallography.Keywords
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