Binuclear organometallic compounds. Part VI. Complexes containing metal–metal bonds between elements of group IVAand group IVB
- 1 January 1972
- journal article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 1,p. 69-73
- https://doi.org/10.1039/dt9720000069
Abstract
The isolation of stable complexes (cp)2M(Cl)M1Ph3(cp =π-C5H5; M = Zr or Hf; M1= Si or Ge) is described. Spectroscopic data and some M–Si cleavage reactions are reported. The complexes are of interest as d° complexes having metal–metal bonds and with the transition metal in a high (+4) oxidation state.Keywords
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