Rearrangement of allylic silylsulphonium ylides. A synthesis of βγ-unsaturated aldehydes
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1096-1097
- https://doi.org/10.1039/c39800001096
Abstract
The ylides derived from the reaction of allylic silylmethylsulphonium salts with n-butyl-lithium rearrange to homoallylic α-methylthiosilanes which are precursors to βγ-unsaturated aldehydes.Keywords
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