Vacuum ultraviolet emission by active nitrogen. III. The absolute rates of population of N2(a1Πg) and CO(A1Π)
- 26 September 1972
- journal article
- Published by The Royal Society in Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
- Vol. 330 (1580) , 109-120
- https://doi.org/10.1098/rspa.1972.0134
Abstract
A study of the detailed kinetics and particularly the CO2quenching of CO fourth positive emission from active nitrogen has yielded individual rate coefficients for the energy transfer from N2(a1Πg),v= 0, 1 and 2 to CO(A1Π),v= 0 - 4. These do not follow any simple pattern. At high CO concentrations, an additional population of CO(A1Π),v= 1 and 6 from high levels of N2(a1Πg) and (a'1∑u-) occurs via the intermediacy of CO(I1∑-).Keywords
This publication has 7 references indexed in Scilit:
- Collisional Deactivation of CO (a 3Π)The Journal of Chemical Physics, 1971
- Mechanism of the Chemiluminescent Emission of the CO Fourth Positive Bands in Active Nitrogen/CO MixturesThe Journal of Chemical Physics, 1971
- Rates of energy transfer from N2 A 3? + u to various molecules. Initial and final quantum states in the transfer to NOX 2? and Hg(61 S 0), and vibrational relaxation of N2 A 3? + u (v= 1) in heliumTransactions of the Faraday Society, 1971
- Chemical Applications of Metastable Argon Atoms. IV. Excitation and Relaxation of Triplet States of N2The Journal of Chemical Physics, 1970
- Resonance Fluorescence and Xenon Sensitization of the CO(A 1II→X 1Σ+) SystemThe Journal of Chemical Physics, 1969
- The Fourth Positive System of Carbon Monoxide Observed in Absorption at High Resolution in the Vacuum Ultraviolet RegionThe Astrophysical Journal, 1969
- THE FORBIDDEN I1Σ−–X1Σ+ ABSORPTION BANDS OF CARBON MONOXIDECanadian Journal of Physics, 1966