4-Alkyl-thio- and -dithio-azetidinones from penicillins

Abstract
Thiols react smoothly with penicillin sulphoxides to form 4-alkylthioazetidinones which, by treatment with phosphites or reaction with nucleophiles and alkyl iodides, afford 4-alkylthioazetidinones; some related reactions are also reported.

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